SEMINAR
DEPARTMENT OF CHEMICAL ENGINEEERING
NORTH CAROLINA STATE UNIVERSITY

Monday, March 5, 2001
11 Riddick - 10:10 AM

Dynamics and Rheology of Polymer and Surfactant Solutions in Suppressing Aerosol Formation

Esin Gulari
Wayne State University

The effect of dissolving high molecular weight polymers in liquids at very low concentrations is to make the liquid slightly elastic and thus providing an effective method of controlling aerosol formation. The breakup or atomization of slightly elastic liquid produces larger drops or prevents formation of drops depending on the applied stresses. There are many industrial processes where controlling the formation of small drops is very important. Such processes include ink-jet printing, agricultural spraying and metal cutting operations.

In this seminar, the results of experiments designed to elucidate the mechanisms of aerosol formation through controlled atomization and elongational rheometry are presented. The choice of systems target the type of fluids used in metal working operations in the automotive industry. However, these systems exhibit fundamental variations in complexity, from binary polymer solutions to ternary associating polymer-surfactant and polymer-polymer solutions. For all systems, the increase in average drop size, due to dissolved polymer or polymer-surfactant mixture in the liquid, strongly correlates to the elongational viscosity of the solution.